Acidity regulator E330 citric acid. Lemon acid. Food additive E330. Use in everyday life

Today you will hardly surprise anyone with food additives that have become firmly established in our lives.

Despite the generally negative attitude towards additives, some of them, for example, E-330, do not have a negative effect on the human body and can be found in natural products.

Citric acid, coded E-330, belongs to the group of natural antioxidants. It has a characteristic sour taste and is involved in human metabolic processes. It is a white crystalline powder, highly soluble in water and alcohols.

When heated to a temperature of more than 175 degrees, the acid decomposes into molecules of water and carbon dioxide. Currently, the substance is extracted from a variety of products: sugar, lemon, molasses, pineapple waste, etc.

Since extracting acid powder from citrus fruits proved expensive on an industrial scale, the synthesis of the material from chemicals was developed, which had a major impact on the development of canning industries throughout the world.

Use in everyday life

E330 is widely used not only in everyday life, but also in industrial production in the food and cosmetics industries. As a flavoring additive, it does not cause harm at all, but only a positive effect on our body, when consumed in moderation. It can be found in most juices and juice-containing products, and in confectionery products.

In cosmetics, E330 is contained as a pH acidity regulator in such preparations as:

  • shampoos;
  • lotions;
  • cosmetic creams;
  • elixirs;
  • hairsprays and more.

The spread of citric acid was favored by the antioxidant properties discovered in it in the middle of the last century. Today, every person can find acid-containing deodorants and lotions on their dressing table, which provide not only skin protection, but also proper disinfection.

Thanks to its ability to dissolve calcium salts, citric acid is found in most of our everyday detergents and cleaning products. Without using much effort, with its help we can easily remove almost any household scale and do not cause harm to all kinds of metal and ceramic surfaces. This action and influence of the additive made it possible to use it in oil production.

Beneficial properties of citric acid

This supplement has a positive effect on cellular respiration; it actively takes part in cell renewal. Our body and, in particular, our skin have a lot to thank it for, since the elasticity of the top layer improves and the number of wrinkles decreases. Accumulated toxins and toxic substances come out through the pores.

In addition, citric acid is added to fats and margarines to prevent them from going rancid. It has become indispensable in the food industry due to its preservative properties. The substance E330 is used as a leavening agent for dough - in combination with baking soda, carbon dioxide is released, which gives the dough additional airiness.

Most known microbes are unable to survive in an acidic environment and therefore cause harm and negative effects on the human body, which is why acid powder is added as a preservative to many types of foods. With the help of acid, manufacturers manage to regulate the taste and color of a number of products, and the substances contained in it neutralize them from the breakdown of heavy metal particles.

What might cause concern?

Doctors substantiated the effect of the substance on humans and began to use it to improve metabolic and energy exchange processes. Some harm may occur if significant amounts of the drug are consumed.

First of all, when a chemical compound is ingested, gradual destruction of tooth enamel occurs, accompanied by the development of caries. When a large dose of acid enters the body once, burns of the digestive organs occur, which causes vomiting, as well as irritation of the respiratory tract.

Contact with the surface of the eyes or skin provokes a chemical burn. Small amounts of E330 can have a beneficial effect on the adult body, because it has antibacterial and anti-aging properties. But its excessive concentration is contraindicated for persons suffering from diseases of the gastrointestinal tract, to whom acid causes significant harm.

Despite the fact that E330 has been approved by the world's main health organizations and is permitted as a food additive even in the European Union, the rule of the golden mean is valid in this case as well. The permissible daily dose of the supplement should not exceed 100-115 mg per 1 kilogram of body, so that its beneficial properties do not cause harm to each of us.

Name: Citric acid E330
Other names: E330, E-330, English: E330, E-330, Citric Acid
Group: Food additive
Type: Antioxidants, antioxidants
Effect on the body: useful
Approved in countries: Russia, Ukraine, EU

Characteristic:
At its core, citric acid E330 or Citric Acid is an antioxidant that belongs to organic acids. This food supplement can be obtained from natural ingredients or synthetically. In nature, citric acid is found in pomegranates, pineapples, cranberries, citrus fruits, pine needles, and tobacco plants. E330 is recognized by its pronounced sour taste and is recognized as a natural preservative.
Citric acid appears in the form of white crystals, easily soluble in water and alcohol. Practically insoluble in diethyl ether. When heated to 153°C, the E330 additive begins to melt. If you place it in an environment with a temperature of 175°C, citric acid decomposes into water and carbon dioxide.
This food supplement was discovered in 1784 by the Swedish scientist Karl Scheele. After it began to be produced in large quantities in production, E330 became indispensable in the food industry.

Application:
Citric acid plays the role of an acidity regulator, preservative and flavoring agent at the same time. It has occupied a niche in the production of food products, cosmetics, chemical detergents and cleaning products and medicine. Drinks, juices, sweets, baked goods, confectionery, they all contain E 330.
Doctors use citric acid to improve metabolic processes and energy metabolism.
Cosmetology is also unthinkable without the additive E-330. Citric acid is an essential component of creams, hair sprays and gels, foams, shampoos, lotions, and bath foams. It plays the role of an acidity regulator.
Oil workers use citric acid in the process of drilling both gas and oil wells. The additive neutralizes cement in the solution and removes calcium ions from the drilling fluid.
Citric acid is approved for use in all countries.

Effect on the human body:
In small doses, citric acid E330 has a positive effect on the human body and is present in vital metabolic metabolic processes.
But there is also a health hazard with large doses of E330. For example, citric acid concentrate upon contact with skin or eyes leads to severe chemical burns, or even loss of vision. If a person consumes too much E330 with food, then the enamel of the teeth suffers, and there is a threat of developing caries. If too large a dose of acid enters the body at one time, then, as a consequence, a cough, vomiting with blood and a burn of the esophagus and stomach may develop. If the additive gets into the respiratory tract, severe irritation is observed.

Citric acid is a food additive with index E331, a representative of the group of antioxidants. The substance is a white, water-soluble powder with a pronounced sour taste.

The substance was first obtained in 1784 from lemon juice, after which its industrial production began from lemons and chewing tobacco (shag). Natural sources of citric acid also include rose hips, sweet red peppers, cranberries, and citrus fruits.

However, today this food additive is produced chemically, synthesizing sugary substances with strains of mold fungi Aspergillus niger, or by fermenting molasses. The resulting substance is crystallized and dried.

Use of citric acid for food

The food additive E330 is widely used in the production of food and household chemicals, in pharmacology and cosmetology. The substance is simultaneously an antioxidant, acidity regulator, preservative and color stabilizer.

Citric acid is found in the following products:

  • meat and fish products;
  • canned and frozen vegetables and fruits;
  • oils, fats;
  • confectionery;
  • bakery products;
  • soft and alcoholic drinks.

The food additive E330 improves the quality of flour, is included in the composition of baking powder, and protects vegetables and fruits from rapid rotting. In addition, it plays the role of a color fixer, taste improver and acidity regulator.

In cosmetology, citric acid is used as an antioxidant and pH regulator. Additive E330 is included in shaving products, creams, anti-aging masks, cosmetic lotions, and helps fight oily skin and fine wrinkles. In households, the substance is used as a cleaning and disinfectant.

The benefits and harms of citric acid for the human body

The food additive E330 is recognized as safe for health and is approved for use in all countries. This substance is present in the human body as a product of fat breakdown. Citric acid is involved in the metabolic process, provides the body with energy, improves immunity, and is necessary for normal cell renewal and the removal of toxins.

Only large doses of citric acid cause harm to the body. High concentrations of citric acid E330 cause tooth decay, neutralizing calcium, and provoke allergic reactions when it comes into contact with the skin. Eating citric acid is not recommended for people suffering from gastrointestinal diseases.

Citric acid is a chemical constituent of many plants. Most of it is found in rose hips (470 mg/100 g) and sweet red pepper (250 mg). The lemon, which gives the additive its name, contains only 40 mg.

Once upon a time, the acid was isolated from citrus fruits and fermented green mass of shag. The yield of the finished substance was small and very expensive.

The value of the powerful antioxidant was so significant that work on finding and implementing a cheap production method and increasing the total amount of the target product did not stop even during the Second World War.

Citric acid is available in two types: food grade and technical grade.

The name of the additive for food production and the conditions for its use are regulated by GOST 31726–2012. The document will be valid in a new edition from January 1, 2017.

The antioxidant is called anhydrous citric acid E 330.

The numbers indicate the code assigned to the additive by the European Union. In some documents the spelling E-330 is found.

You can find other names:

  • citric acid anhydrous E330, international designation;
  • 2-Hydroxy-1,2,3-propanetricarboxylic acid, chemical name;
  • citric acid; p-hydroxytricarballytic acid, English synonyms,
  • citronensaure (another spelling zitronensaure), German;
  • acide citrique, French.

Type of substance

Food additive E 330 is a representative of the group.

The uniqueness of citric acid is that, according to its technological properties, it can be classified into several categories:

  • antioxidant (quickly binds free radicals, stopping peroxidation);
  • (almost all known pathogenic microbes die in an acidic environment);
  • acidity regulator;
  • color stabilizer.

According to the chemical structure, food additive E 330 is a tribasic hydroxycarboxylic acid.

Citric acid is obtained from carbohydrate-containing raw materials: beet molasses, starches (corn, wheat, potato). The starting products are fermented with certain selected strains of the mold fungus Aspergillus niger. The output is a culture liquid containing up to 90% citric acid.

It is separated from other impurities using chemically precipitated chalk or lime milk (a mixture of slaked lime and water). After purification, the acid is evaporated in a vacuum unit, crystallized, dried and packaged.

The chemical method of obtaining the food additive E 330 does not give the right to classify it as a natural product, despite the use of natural raw materials at the first stage.

Properties

Index Standard values
Color white
Compound hydroxycarboxylic acid, impurities (oxalate, sulfate); empirical formula C 6 H 8 O 7
Appearance crystalline powder
Smell absent
Solubility good in water, alcohols; bad on air
Main substance content 99,5%
Taste sour
Density 1.66 g/cm 3
Other thermally unstable, subject to decomposition when heated

Package

Citric acid is packaged in bags made of dense polyethylene film, grade N, intended for packaging food products (GOST 19360). Once filled, the bags are sealed to ensure a tight seal.

The outer containers are:

  • grocery bags;
  • three-layer paper bags, grade NM (unimpregnated);
  • cardboard boxes made of corrugated material.

The use of other types of packaging materials is permitted.

The food additive E 330 is approved for retail sale. Citric acid is supplied in paper bags of 5 g and boxes (plastic or cardboard) of any size.

Application

In the food industry

The main consumer of the E 330 additive is the food industry.

Citric acid protects foods from spoilage and improves their taste.

The variety of properties and easy interaction with others allow the use of citric acid in the production of a large number of food products:

  • bakery products (for acidification, improving the quality of flour, as a component of baking powder);
  • canned, frozen, fresh vegetables and fruits (including surface treatment to protect against infection by putrefactive bacteria);
  • confectionery products (including for the production of invert syrup);
  • carbonated drinks, juices, nectars (pH regulator)
  • chocolate and cocoa products (to stabilize consistency);
  • cheeses;
  • fish products;
  • bouillon cubes (as a hydrolysis catalyst);
  • meat products (extending shelf life, color fixative);
  • vegetable oils, animal fats (as a lipid antioxidant);
  • alcoholic drinks (including beer).
  • The list is far from complete.
Citric acid is allowed to be used as an acidity regulator in human milk substitutes and complementary feeding formulas for children over 5 months (2g/l).

Codex Alimentarius allows the use of food additive E 330 in 70 standards.

In cosmetics

The cosmetics industry is not lagging behind the food industry.

Citric acid acts as a synergist with other antioxidants. It is usually introduced into preparations together with, or acid under the general name “Fruit acids”.

On the packaging of many skin care products, shampoos, and anti-aging cosmetics you can see the phrase “Using AHA acids.” The ingredient is positioned as an innovative additive that whitens and deeply cleanses the skin.

Manufacturers are a little disingenuous. Mysterious letters indicate the same fruit acids that have been known for centuries.

Supplements really are strong biostimulants.

The antibacterial properties of the E 330 additive are used by manufacturers of men's hygiene cosmetics. Deodorants, lotions and sprays with citric acid disinfect the skin and normalize the acid balance.

Other

Other applications:

  • pharmacology (in drugs that improve metabolism);
  • household chemicals (scale removers);
  • petrochemical industry (to reduce the acidity level of drilling fluid);
  • construction industry (additive to cement to prevent premature setting).

Benefits and harms

Citric acid is present in any living organism as an intermediate product during the breakdown and synthesis of proteins and fats.

Its main function is to provide the body with energy. It is completely digestible and is considered safe as the mildest among carboxylic acids. The permissible daily intake has not been established.

Beneficial properties of food antioxidant E 330:

  • removes toxins;
  • participates in cell renewal;
  • increases immunity;
  • reduces the risk of developing cancer.

Citric acid as an additive to cosmetics:

  • successfully copes with acne, cleansing and tightening pores;
  • gently exfoliates dead skin cells of the epidermis;
  • promotes collagen production, has a rejuvenating effect;
  • removes fine wrinkles;
  • improves complexion.

Harm associated with consuming large amounts of citric acid. The concentrated solution may cause:

  • burn of the esophagus;
  • destruction of tooth enamel. Dentists advise rinsing your mouth with clean water after drinking citric acid;
  • allergic reactions upon contact with skin.
People with gastrointestinal problems should use the E 330 food supplement with caution. Citric acid can cause exacerbation of diseases.

The Kedr group, based on the results of its own independent examination, classified the food additive E 330 as a carcinogen with the caveat that only large doses of the substance are dangerous.

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Main manufacturers

50% of supplied citric acid is produced by Chinese enterprises.

The remaining share of production is distributed between Russia, the USA, and France.

Main manufacturers:

  • Citrobel LLC (formerly the Belgorod Citric Acid Plant), the company's share accounts for 40% of the citric acid on the domestic market;
  • Anhui Fengyuan Biochemical Co. Ltd (China);
  • agro-industrial corporation Archer Daniels Midland (USA).

The healing power of lemon has been known since ancient times. Prudent Egyptians generously added it to their food not only for the fullness of taste. Sour fruits neutralized the effects of poisons, which in difficult times were usually mixed into food for enemies.

The absence of traces of lemon in the modern food additive E 330 does not detract from its advantages. The taste and medicinal properties of artificial citric acid allow us to consider it one of the most useful.

You just have to remember the need to observe moderation.

Citric acid is perhaps the most popular food additive, which can always be found in almost every home. Many housewives know a variety of ways to use this substance for various other household purposes (besides cooking). However, its properties are so diverse and amazing that it is worth telling about it in more detail.

General characteristics and formula

The chemical name of the substance will probably seem difficult to pronounce to a non-specialist. Try this without prior training:“two-hydroxy-one-two-tri-propanetricarboxylic acid” or, when visiting, ask your neighbor to give you THIS to add to okroshka. By the way, the English version sounds much simpler: “citric acid”.


The formula of the substance looks no less impressive: HOOC-CH2-C(OH)COOH-CH2-COOH or (HOOCCH2)2C(OH)COOH or, simplified, C6H8O7. For those who remember even a little school chemistry lessons, it is clear from this formula that we are talking about an organic substance. Three carbon atoms, six oxygen atoms and three hydrogen atoms in it form three carboxyl groups (COOH), that is, we are talking about a tribasic carboxylic acid.

However, for the purposes of our article, it is not the names and formulas that are interesting, but, first of all, the physical properties of this substance.

Did you know? The substance received its name due to the fact that it was first isolated from the juice of unripe lemons. We owe this important discovery for all mankind, which was made back in 1784, to the Swedish chemist and pharmacist Karl Scheele.

Everyone knows what the substance looks like. It is a white crystalline powder. In dry form, it has a melting point of +153 °C, its density is 1.542 g/cm3.

It is perfectly soluble in water, even at room temperature 132 g of the substance can be dissolved in 100 ml of water, in addition, it dissolves well in ethyl, methyl and propyl alcohol, hydrogen fluoride, formic acid, diethyl ether, dioxane, dimethyl sulfoxide. Insoluble in chloroform, toluene, carbon disulfide, benzene.


At a temperature of +175 °C, the substance forms aconitic (A) and acetone dicarboxylic (B) acids in the mixture, and upon subsequent heating - itaconic acid(it is formed due to the removal of one hydrogen particle).

During dry distillation, decarboxylation of the substance occurs (elimination of carbon dioxide and evaporation of water), resulting in the formation of acetone and anhydrides of itaconic and citraconic acid, and when calcined with alkali, salts of oxalic and acetic acid.

Citric acid salts(citrates) are formed by replacing hydrogen with the acyl residue RCO.

Due to the remoteness of the extreme carboxyl groups from each other, the substance does not actively participate in various chemical reactions, and therefore is considered a weak acid.


Sources of citric acid

The organic substance in question is quite widespread in nature, and it is found not only in lemons, where its amount can reach 8%, but also in other citrus fruits.

In addition, citric acid is also found in:

  • (tomatoes, artichokes, some varieties of peppers);
  • berries (almost all except blueberries:);
  • pine needles, Chinese lemongrass, cotton and shag. Interestingly, it is also present in the tissues of many protozoa.

Important! The sour taste of most vegetables and fruits is given not by citric acid, but by ascorbic acid (vitamin C).

It should be said that earlier (until the 20s of the twentieth century), the organic supplement, however, was obtained mainly from lemons. However, this method is quite expensive: in order to obtain 100 kg of the substance, you need to process at least four tons of valuable citrus fruits.


Therefore, today it is synthesized artificially. To do this, sugary substances, waste from sugar production, are artificially infected with a special mold fungus of the genus Aspergillius niger (for convenience, very often such production is carried out directly at sugar factories).

What are the benefits of the supplement?

Citric acid as a food additive has many beneficial properties. Like , this substance is the strongest natural substance and, therefore, helps strengthen protection against negative environmental factors. In moderate doses, it does not affect the mucous membranes of the digestive system, but it perfectly stimulates its functioning, in addition, it helps eliminate harmful substances, free radicals, salts and other nasties (including alcohol toxins, which is why it is used for hangover syndrome), inhibits the development of atypical cells and even improves vision.

Once in the stomach and absorbed into the blood, the acid has a stimulating effect on all metabolic processes, which is why it is often used in various methods of quick and healthy weight loss.


Men will be interested to know that this dietary supplement helps improve sperm quality and, accordingly, makes pregnancy more likely. By the way, a mother expecting the birth of a baby, on the contrary, should refrain from consuming citric acid, especially if pregnancy is accompanied by heartburn, nausea, pressure surges and allergic dermatitis.

Areas of application of E330

In industry, citric acid known as food additive E330(officially registered food symbol).

Did you know? Interestingly, in the 70s of the last century, the food additive E330 was included in the so-called Villejuif list as a substance hazardous to health (carcinogen). Undeserved accusations against it were finally dropped only twenty years later, and until that moment, all of civilized Europe and even many states in Africa and the Middle East considered it poison.

Fortunately, today doubts have been completely dispelled, and the organic substance E330 is successfully used not only in the food industry and in everyday life, but even in cosmetology and medicine.

In medicine

The ability of the food additive E330 to improve energy metabolism has found practical application in the pharmaceutical industry.


Sodium citric acid(sodium citrate, official symbol E331) is a proven remedy for stabilizing blood reserves, as well as for the treatment of cystitis. The same drug is used in laboratory blood tests to determine the erythrocyte sedimentation rate (ESR).

Traditional medicine recommends using a 30% solution of citric acid to gargle for sore throat. As an alternative method, you can use regular lemon; you just need to chew it slowly and swallow it with your head thrown back. The antioxidant and bactericidal properties of the acid will help speed up the healing process.

In cosmetology

Organic substance E330 is an essential ingredient in a huge number of cosmetic products.


One of the reasons for the popularity of the supplement- its ability to regulate the pH level in the product. Thus, in addition to the general improvement of the functional effect of cosmetics, a preservative effect is also achieved.

Important! According to regulations in certain countries, E330 may not be included in a product if it is used solely as a pH adjuster. Thus, when using our favorite cosmetics, we may have no idea that citric acid is present in it.

However, in cosmetology this acid also performs many other functions. It helps whiten the skin, expand its pores, and exfoliate dead epidermal cells. Being a natural component, the substance very rarely causes intolerance and other negative reactions. Antioxidant properties help ensure smoothing of wrinkles and an overall rejuvenation effect.

In detergents, E330 promotes better foaming, and in hair dyes it increases color saturation.

No less popular in cosmetology and various derivatives of citric acid, its salts and esters (diammonium citrates, etc.). Esters, due to the formation of a thin protective film on the skin, ensure the preservation of its moisture, due to which they are often added to moisturizing creams. But, for example, an ester such as tributyl citrate is used even in plastic surgery.


When combined with certain minerals, E330 also forms substances having an astringent effect(acne treatment, care for oily and combination skin), ensuring fixation of a cosmetic product when sprayed (hair sprays), preventing the formation of tartar (additives in toothpastes), regulating the acid-base balance, etc.

Acid has found equally widespread use in home beauty recipes. than in professional cosmetology. With its help, skin is cleansed, degreased and lightened, including from various age spots. Adding the substance to hand baths helps strengthen the nail plate and provides nourishment to the skin. In hair masks, acidic crystals are needed to add shine and silkiness (for this purpose, you can simply rinse your hair with water and lemon juice).


In dietetics

The use of citric acid for weight loss is usually motivated by its ability to burn fat. In fact, this is nothing more than a myth.

Important! Citric acid does not burn fat, but only speeds up metabolic processes.

However, the dietary supplement still has nutritional properties. By stimulating metabolism, accelerating blood flow and removing excess salt and liquid from the body, the substance improves the quality of the digestive system, and increasing the viscosity of saliva helps reduce appetite.

However, citric acid-based diets should be approached with great caution. because if used incorrectly it can:


  • cause irritation of the mucous membranes of the throat and digestive system;
  • lead to dehydration and drying out of the body;
  • provoke the occurrence of ulcers and even cancer of the gastrointestinal tract.
To achieve the desired effect, nutritionists recommend providing a proper and balanced diet, excluding salted, smoked and fried foods, and at the same time drinking water with citric acid dissolved in it, gradually increasing the concentration of the substance in water from half a teaspoon per 300 ml of water to a teaspoon per glass .

At home

Acidic crystals are great for removing scale from dishes, which is why many housewives use this product to clean teapots and pots. A small amount of water is poured into the bottom of the container (the contaminated surface should be completely covered), then 30 g of acid is poured. The dishes are placed on the fire, the water is brought to a boil and drained. The bottom remains mirror clean, and all the scale goes away along with the water.


Important! If you add a little substance to a vase with water before placing a bouquet in it, cut flowers will remain fresh much longer: the acid will kill microbes, “preserve” the stems and additionally nourish them.

This product is also used for cleaning washing machines and irons.

Contraindications and harm

Like any other acid, the E330 additive is not completely harmless, however, the danger lies primarily in its misuse and overdose.

Initially, the mucous membranes suffer from the excess of the substance. Symptoms of an overdose of citric (as well as ascorbic) acid are:


  • severe pain and cramps in the abdomen or stomach;
  • cough;
  • nausea and vomiting, sometimes with blood;
  • diarrhea (in severe cases - with bloody spots);
  • swelling;
  • increased sweating;
  • loss of appetite;
  • increased fatigue;
  • yellowing of the skin and whites of the eyes;
  • frequent urination;
  • increase in body temperature;
  • headache;
  • increased blood pressure;
  • change in emotional state from nervousness and anxiety to weakness and apathy.

Important! Theoretically, an overdose of citric acid can be fatal. Thus, a lethal dose of the drug for rats and mice is considered to be 6-7 g of the substance, and 20 g of the additive can kill an adult.

Long-term uncontrolled use of citric acid can, in addition, lead to the destruction of tooth enamel.


Even in moderate quantities, the additive can cause harm to people suffering from diseases of the gastrointestinal tract in the acute stage, it is especially dangerous when.

So, citric acid is an excellent helper in solving everyday problems, it is very widely used in cooking and cosmetology, and is also used in medicine and dietetics. To ensure that this substance does not cause harm, you just need to follow the usual precautions and avoid overdosing when using the supplement.



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